| 一些光敏剂水溶液体系光生电势与光催化产氢的关系 |
| |
| 引用本文： | 毕只初,钱越英,俞稼镛. 一些光敏剂水溶液体系光生电势与光催化产氢的关系[J]. 感光科学与光化学, 1990, 0(3) |
| |
| 作者姓名： | 毕只初 钱越英 俞稼镛 |
| |
| 作者单位： | 中国科学院感光化学研究所，中国科学院感光化学研究所，中国科学院感光化学研究所 北京 100101，北京 100101，北京 100101 |
| |
| 摘 要： | 在太阳能分解水制氢研究中存在的一个问题,是产氢要消耗化学试剂(电子给体),以人们研究得很多的Ru(bpy)_3~(2+)-MV~(2+)-EDTA-铂催化剂体系为例,光照下产氢时,其净的化学反应为:
|
| 关 键 词： | 光敏剂 电子给体 光生电势 光照产氢 |
ON THE RELATIONSHIP BETWEEN THE PHOTOPOTENTIAL AND H_2 PHOTOPRODUCTION OF SOME AQUEOUS SOLUTIONS OF PHOTOSENSITIZER-ELECTRON DONOR |
| |
| BI ZHI-CHU QIAN YUE-YING Yu JIA-YONG. ON THE RELATIONSHIP BETWEEN THE PHOTOPOTENTIAL AND H_2 PHOTOPRODUCTION OF SOME AQUEOUS SOLUTIONS OF PHOTOSENSITIZER-ELECTRON DONOR[J]. Photographic Science and Photochemistry, 1990, 0(3) |
| |
| Authors: | BI ZHI-CHU QIAN YUE-YING Yu JIA-YONG |
| |
| Abstract: | Phototentials (EL) of proflavin-EDTA,acridine yellow- EDTA,and erythrosin-TEOA aqueous solutions were measured by using SnO2 as working electrode and SCE as reference electrode.EL was compared with the potential of H2 electrode (EH+/H,) at the pH of the photosensitizer-electron donor aqueous solution.It was found that EL>EH+/H2was the crucial condition for a photosensitizer-donor solution to make H2 photoproduction in the presence of K2PtCl6 For the same Ru(bpy)32+-MV2+-EDTA aqueous solution,it has also been found that the higher its photopotential at different pH of the solution or different concentrations of a component in the solution,the higher its rate of H2 photoproduction in the presence of Pt catalyst. |
| |
| Keywords: | photosensitizer electron donor photopotential hydrogen photoproduction |
| 本文献已被 CNKI 等数据库收录！ |
