Methane partial oxidation to methanol-solid initiated homogeneous methane oxidation |
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| Authors: | K Omata N Fukuoka K Fujimoto |
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| Affiliation: | (1) Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, 113 Tokyo, Japan |
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| Abstract: | The initiation temperature of methane partial oxidation was markedly lowered by platinum wire placed upstream of a high pressure reactor. Added hydrogen in the reactant gas promoted the methanol selectivity. The radicals formed on the platinum surface were desorbed from it and initiated the reaction. |
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| Keywords: | Methane oxidation homogeneous reaction platinum methanol formation hydrogen effect |
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