Study on a green synthetic method of TRPPMCl (M = Fe, Mn, Co) |
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Authors: | Jing Fan Yuanbin She Aixin Wang |
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Affiliation: | (1) Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing, 100124, China |
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Abstract: | A green synthetic method using mixted solvents of di-methyl formamide (DMF) and acids instead of single DMF to synthesize metalloporphyrins (TRPPMCl) from TRPPH2 and MCl2 metallization was proposed in this paper. A series of TRPPMCl (M = Fe, Mn, Co) were synthesized through this innovative synthetic method, and these complexes were characterized with various spectroscopic techniques, including IR and UV-Vis spectroscopy. The results showed that the metallization time was markedly reduced from about 10 h to 0.5 h in contrast with the conventional synthetic methods. |
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Keywords: | TRPPMCl metalloporphyrins green synthesis acid |
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