| 戊菌唑和烯唑醇对映异构体的直接手性拆分 |
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| 引用本文： | 韩小茜,温晓光,管永红,陈立仁.戊菌唑和烯唑醇对映异构体的直接手性拆分[J].化学试剂,2004,26(2):69-70,86. |
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| 作者姓名： | 韩小茜 温晓光 管永红 陈立仁 |
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| 作者单位： | 兰州交通大学,化学与生物工程学院,甘肃,兰州,730070;中国科学院,兰州化学物理研究所,甘肃,兰州,730000 |
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| 基金项目： | 中国科学院“百人计划”资助项目 |
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| 摘 要： | 戊菌唑及烯唑醇对映异构体在自制的直链淀粉-三(苯基氨基甲酸酯)手性固定相获得了拆分。通过选择不同结构、不同碳数的醇做流动相的极性改性剂，优化了色谱分离结果。考察了分离温度对戊菌唑对映异构体手性拆分的影响。
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| 关 键 词： | 直链淀粉-三(苯基氨基甲酸酯) 手性固定相 手性拆分 戊菌唑 |
| 文章编号： | 0258-3283(2004)02-0069-02 |
The chiral separation of diniconazole and penconazole on amylose ( phenykarbamate) chiral stationary phase |
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| HAN Xiao-qian,WEN Xiao-guang,GUAN Yong-hong,CHEN Li-ren.The chiral separation of diniconazole and penconazole on amylose ( phenykarbamate) chiral stationary phase[J].Chemical Reagents,2004,26(2):69-70,86. |
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| Authors: | HAN Xiao-qian WEN Xiao-guang GUAN Yong-hong CHEN Li-ren |
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| Affiliation: | HAN Xiao qian *1,WEN Xiao guang 1,GUAN Yong hong 1,CHEN Li ren 2 |
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| Abstract: | The chiral separation of racemic diniconazole and penconazole was achieved on amylose (phenylcarbamate) chiral column,which was prepared in our lab.The chromatographic conditions were optimized using different alcohols as mobile phase modifier.The effect of temperature on chiral separation was investigated. |
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| Keywords: | amylose (phenylcarbamate) chiral stationary phase chiral separation pesticide diniconazole penconazole |
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