| 8-羟基喹啉合铜(II)配合物的合成与结构表征 |
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| 引用本文： | 郑国侠,薛静波.8-羟基喹啉合铜(II)配合物的合成与结构表征[J].青岛科技大学学报,2003(5). |
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| 作者姓名： | 郑国侠 薛静波 |
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| 作者单位： | 青岛科技大学化学与分子工程学院 山东青岛266042
(郑国侠)，青岛科技大学化学与分子工程学院 山东青岛266042(薛静波) |
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| 摘 要： | 8-羟基喹啉与过渡金属离子铜 ( II)配合反应生成 8-羟基喹啉合铜 ( II)配合物 ,在其 DMF溶液中培养出单晶。通过 X-射线衍射分析测定其分子结构。该配合物属于单斜晶系 ,空间群 P2 1/c。晶胞参数为 a=1 0 .648( 2 ) ,b=8.60 70 ( 1 7) ,c=1 5 .2 5 5 ( 3) ,β=1 0 2 .2 4°,V=1 366.3( 5 ) ,Dc=1 .71 0 g· cm- 3,Z=4。在晶体结构中 ,铜 ( II)分别与两个 8-羟基喹啉的两个氧原子及两个氮原子相连
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| 关 键 词： | 8-羟基喹啉合铜(II) 配合物 单晶 晶体结构 |
Synthesis and Characterization of Complex Between Copper(II) and 8-Hydroxyquinolie |
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| ZHENG Guo Xia,XUE Jing Bo.Synthesis and Characterization of Complex Between Copper(II) and 8-Hydroxyquinolie[J].Journal of Qingdao University of Science and Technology:Natutral Science Edition,2003(5). |
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| Authors: | ZHENG Guo Xia XUE Jing Bo |
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| Abstract: | The copper(Ⅱ) complex with 8 hydroxyqainoline was prepared by the reaction of 8 hydroxyquinolme with copper(Ⅱ) Its single crystal was obtained by.The structure of the complex was characterized by X ray crystallography.The results show that the complex is of the monoclinic system and the space group is P 2 1 / c ,The lattice parameters are as following: a =10.648(2), b =8.6070(17), c =15.255(3), β =102.24°, V =1366.3(5), Dc =1.710g·cm -3 and Z =4. |
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| Keywords: | Cu(C 9H 6NO) 2 complex complex single crystal crystal structure |
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