Synthesis and spectroscopic properties of (C2FxBr0.01 · yCH3CN)n (0.5 < x < 1.0) intercalation compounds |
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| Authors: | D V Pinakov L A Sheludyakova G N Chekhova N I Alferova L N Mazalov and P N Gevko |
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| Affiliation: | (1) A. V. Nikolaev Institute of Inorganic Chemistry SB RAS, Acad. Lavrentyev ave. 3, 630090 Novosibirsk, Russia |
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| Abstract: | (C2F
x
Br0.01 · yCH3CN)
n
intercalation compounds, with (C2F
x
Br0.01)
n
(0.5 < x < 1.0) as a host and CH3CN as a guest (x and y are stoichiometric coefficients), have been synthesized. The influence of fluorine content on the spectroscopic characteristics
of the intercalation compounds with acetonitrile has been studied by Raman, IR, and X-ray photoelectron spectroscopies. The
macroscopic properties of the intercalation compounds are shown to correlate with their spectroscopic characteristics. The
data for the compounds stored in air for about a year indicate that their surface and interior differ in structure. |
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| Keywords: | |
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