| 蒽醌法制过氧化氢氢化反应动力学研究述评 |
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| 引用本文： | 陈群来. 蒽醌法制过氧化氢氢化反应动力学研究述评[J]. 无机盐工业, 2001, 33(2): 20-22 |
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| 作者姓名： | 陈群来 |
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| 作者单位： | 黎明化工研究院, |
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| 摘 要： | 评述了近年发表的蒽醌法制过氧化氢氢化瓜在动力学研究结果,指出无论是使用镍催化剂或是钯催化剂,在具有工业应用价值的实验范围内,蒽醌的氢化对工作液听 有效蒽醌浓度均为0级反应,对氢气分压均为1级反应,同时对不同作者的动力学研究结果进行了评价,为正确引用实验结果提供了参考。
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| 关 键 词： | 过氧化氢 蒽醌法 氢化反应动力学 反应级数 |
| 文章编号： | 1006-4990(2001)02-0020-03 |
| 修稿时间： | 2000-11-11 |
REVIEW OF THE HYDROGENATION KINETICS IN THE PRODUCTION OF HYDROGEN PEROXIDE BY ANTHRA QUINONE PROCESS. |
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| CHEN Qunlai. REVIEW OF THE HYDROGENATION KINETICS IN THE PRODUCTION OF HYDROGEN PEROXIDE BY ANTHRA QUINONE PROCESS.[J]. Inorganic Chemicals Industry, 2001, 33(2): 20-22 |
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| Authors: | CHEN Qunlai |
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| Abstract: | The hydrogenation kinetics for producing hydrogen peroxide by anthraquinone process are reviewed.For both raney nickel catalyst and palladium catalyst,within the experimental scope of industrial interest,the hydrogenation of anthraquinone is zero-order reaction to the concentration of quinones in working solution and first-order reaction to the partial pressure of hydrogen.The kinetics results from different authors are further examined for providing a reference to the proper use of them. |
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| Keywords: | hydrogen peroxide anthraquinone process hydro-genation kinetics reaction order |
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