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Porous sheet-like and sphere-like nano-architectures of SnO2 nanoparticles via a solvent-thermal approach and their gas-sensing performances
Authors:Jie Liu  Xin-Cun Tang  Yuan-Hua Xiao  Hai Jia  Mei-Li Gong  Fu-Qin Huang
Affiliation:1. College of Chemistry and Chemical Engineering, State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;2. State Laboratory of Surface and Interface Science and Technology (SLSIST), Zhengzhou University of Light Industry, Zhengzhou 450002, China
Abstract:Porous sheet-like and sphere-like nano-architectures of SnO2 nanoparticles have been prepared via a solvent-thermal approach in the absence of any surfactant or polymer templates by simply changing the volume ratio of DMF to water. The nano-materials have been characterized by FESEM, XRD, IR, TEM and BET. A mechanism for the formation of nano-architectures is also proposed based on the assembly behaviors of DMF in water. The gas sensors constructed with porous sphere-like SnO2 nano-architectures exhibit much higher sensitivity to the reduce vapors tested, compared to those from porous sheet-like SnO2 materials, while the sheet-like materials show better selectivity to ethanol. The nano-architectures fabricated with the facile method are promising candidates for building chemical sensors with tunable performances.
Keywords:SnO2 nano-architectures   Sheet-like   Sphere-like   Controlled synthesis   Gas sensor
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