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Hydrothermal synthesis of carbon nanotube/cubic Fe3O4 nanocomposite for enhanced performance supercapacitor electrode material
Authors:Dahui Guan  Zan Gao  Wanlu Yang  Jun Wang  Yao Yuan  Bin Wang  Milin Zhang  Lianhe Liu
Affiliation:1. Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, Harbin Engineering University, 150001, PR China;2. Institute of Advanced Marine Materials, Harbin Engineering University, 150001, PR China
Abstract:Carbon nanotube/Fe3O4 (CNT/Fe3O4) nanocomposite with well-dispersed Fe3O4 nano-cubes inlaid on the surfaces of carbon nanotubes, was synthesized through an easy and efficient hydrothermal method. The electrochemical behaviors of the nanocomposite were analyzed by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronopotentiometry in 6 M KOH electrolyte. Results demonstrated that CNT as the supporting material could significantly improve the supercapacitor (SC) performance of the CNT/Fe3O4 composite. Comparing with pure Fe3O4, the resulting composite exhibited improved specific capacitances of 117.2 F/g at 10 mA/cm2 (3 times than that of pure Fe3O4), excellent cyclic stability and a maximum energy density of 16.2 Wh/kg. The much improved electrochemical performances could be attributed to the good conductivity of CNTs as well as the anchored Fe3O4 particles on the CNTs.
Keywords:Carbon nanotube  Iron oxide  Composite material  Supercapacitor
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