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C-rate performance of silicon oxycarbide anodes for Li+ batteries enhanced by carbon nanotubes
Authors:J. ShenD. Ahn  R. Raj
Affiliation:a Department of Mechanical Engineering, University of Colorado, Boulder, CO 80309-0427, United States
b PDC-Energy, Lousville, CO, United States
Abstract:We show that employing single wall carbon nanotubes (CNTs) as the conducting agent significantly increases the capacity of silicon oxycarbide anodes at high C-rates. In these anodes 515 mAh g−1 can be extracted in just over 3 min. The capacity decreases to 300 mAh g−1 at the same extraction rate when carbon black is used as the conducting agent. The CNT anodes have good cyclic stability, retaining 89.2% of initial capacity after 40 cycles. The coulombic efficiency ranges from 95% to 100%.
Keywords:CNTs   Li ion battery anodes   Silicon oxycarbide   Polymer-derived ceramics
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