C-rate performance of silicon oxycarbide anodes for Li+ batteries enhanced by carbon nanotubes |
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Authors: | J. ShenD. Ahn R. Raj |
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Affiliation: | a Department of Mechanical Engineering, University of Colorado, Boulder, CO 80309-0427, United States b PDC-Energy, Lousville, CO, United States |
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Abstract: | We show that employing single wall carbon nanotubes (CNTs) as the conducting agent significantly increases the capacity of silicon oxycarbide anodes at high C-rates. In these anodes 515 mAh g−1 can be extracted in just over 3 min. The capacity decreases to 300 mAh g−1 at the same extraction rate when carbon black is used as the conducting agent. The CNT anodes have good cyclic stability, retaining 89.2% of initial capacity after 40 cycles. The coulombic efficiency ranges from 95% to 100%. |
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Keywords: | CNTs Li ion battery anodes Silicon oxycarbide Polymer-derived ceramics |
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