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硝基胍发射药的微观力学性能研究
引用本文:杨春海,廖昕,堵平,张放.硝基胍发射药的微观力学性能研究[J].兵工学报,2011,32(10):1237-1242.
作者姓名:杨春海  廖昕  堵平  张放
作者单位:(1.南京理工大学 化工学院, 江苏 南京 210094; 2.四川大学 化学学院, 四川 成都 610064)
摘    要:为了研究硝基胍(NQ)发射药力学性能较差的原因,采用原子力显微镜(AFM)的接触模式和轻敲模式,获得了NQ预浸润法和一次性胶化法制备的NQ发射药样品内切面的形貌、相位和摩擦力信号图片,同时对NQ预浸润法制成的发射药样品进行了力谱分析.用扫描电镜(SEM)得到了NQ预浸润法制备的NQ发射药样品的脆断面照片.通过热机械分析...

关 键 词:物理化学  硝基胍发射药  微观  力学性能

Research on Microcosmic Mechanical Properties of NQ Propellant
YANG Chun-hai,LIAO Xin,DU Ping,ZHANG Fang.Research on Microcosmic Mechanical Properties of NQ Propellant[J].Acta Armamentarii,2011,32(10):1237-1242.
Authors:YANG Chun-hai  LIAO Xin  DU Ping  ZHANG Fang
Affiliation:(1.School of Chemical Engineering,Nanjing University of Science and Technology, Nanjing 210094, Jiangsu, China;2.College of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China)
Abstract:In order to find the reason about inferior mechanical properties of NQ gun propellant(NGP),the topography images,phase images and friction force signal pictures of cut surface of NGP prepared by pre-soaked NQ process(PSNP) and one-off gelatinization process(OOGP) were acquired in Contact Mode and Tapping Mode of atomic force microscopy(AFM).At the same time,the force map of cut surface of NGP prepared by PSNP was obtained and analyzed.The brittle fractured surface picture of sample prepared by PSNP was scanned using the scanning electronic microscope(SEM).The linear expansion coefficients of NGP components were obtained from thermomechanical analysis apparatus(TMA).In conclusion,based on comparative analysis,the results reveal that the inferior mechanical properties of NGP are due to the defects in microstructure of NGP and the dependency of these defects on circumstance temperature.The mechanical properties of NGP could be improved by eliminating these adverse factors whenever possible.
Keywords:physicochemetry  NQ propellant  microcosmic  mechanical properties
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