Kinetics of leaching of zinc ferrite in aqueous hydrochloric acid solutions |
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Authors: | C. NÚñez J. Viñals |
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Affiliation: | (1) Barcelona University, Avda. Diagonal, 645, 28 Barcelona, Spain |
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Abstract: | The dissolution of synthetic samples of zinc ferrite in aqueous hydrochloric acid is stoichiometric. The rate appears to be controlled by a chemical reaction on the solid surface, and dependence of the dissolution rate on hydrochloric acid activity is of the first order. Activation energy of 83 kJ mol-1 was found. Zinc ferrite leaching is a slow solubilization process in the hydrochloric acid treatment of dead-roasted Iberian pyrite ashes. The most favorable conditions are 0.5-1 M HC1 at 90 to 100 ‡C, when preferential solubilization of the spinel phases takes place on the hematitic matrix. Extensive extraction of zinc (~90 pct of total zinc) in one to two hours and low solubilization of iron (~8 pet of total iron) results under these conditions. |
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