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BN/聚砜导热绝缘复合材料的制备及性能
引用本文:杨文彬,张凯,杨序平,白进伟,周元林.BN/聚砜导热绝缘复合材料的制备及性能[J].四川建材学院学报,2011(1):24-27.
作者姓名:杨文彬  张凯  杨序平  白进伟  周元林
作者单位:[1]西南科技大学四川省非金属复合与功能材料重点实验室,四川绵阳621010 [2]西南科技大学材料科学与工程学院,四川绵阳621010 [3]中国工程物理研究院总体工程研究所,四川绵阳621900
基金项目:国家自然科学基金资助项目(10876033)
摘    要:采用粉末混合法制备了BN/聚砜导热绝缘复合材料,用扫描电子显微镜(SEM)、导热系数测试仪和超高电阻微电流测试仪对复合材料的微观形貌、导热性能和电绝缘性能进行了表征。结果表明:硅烷偶联剂改性处理后的BN粉体与聚砜基体之间的相容性较好;BN/聚砜复合材料的导热系数随BN含量的增加而增大,最大可达2.08(W·m^-1·K^-1);表面电阻率和体积电阻率随BN含量的增加而减小,最低值分别为0.82×10^15Ω和1.78×10^15(Ω·cm),具有电绝缘性。

关 键 词:氮化硼  聚砜  复合材料  导热性能  电绝缘性能

Study on Preparation and Property of Thermally Conductive and Electrically Insulating BN/polysulfone Composites
Authors:YANG Wen-bin  ZHANG Kai  YANG Xv-ping  BAI Jin-wei  ZHOU Yuan-lin
Affiliation:1.State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials,Southwest University of Science and Technology,Mianyang 621010,Sichuan,China;2.School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621010,Sichuan,China;3.Institute of System Engineering,China Academy of Engineering Physics,Mianyang 621900,Sichuan,China)
Abstract:Thermally conductive and electrically insulating BN/polysulfone composites were prepared by powder mixture method.Microstructures,thermal conductivity and electrical insulation of BN/polysulfone composites were characterized by scanning electron microscopy(SEM),thermal conductivity test and ultra-high resistivity test,respectively.The results show that there is good compatibility between polysulfone matrix and BN fillers,which have been treated by silicone coupling agent.Thermal conductivity of BN/polysulfone composites is increased with the increasing of BN content,the maximum value of which is 2.08(W·m^-1·K^-1).Surface resistivity and volume resistivity of BN/polysulfone composites are decreased with the increasing of BN content,the minimum values of which are 0.82×10^15 Ω and 1.78×10^15(Ω·cm).
Keywords:BN  Polysulfone  Composite  Thermal conductivity  Electrical insulation
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