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钛柱撑蒙脱石对罗丹明B的吸附性能
引用本文:何正先,张宝述,彭同江,孙红娟,董发勤,宋绵新.钛柱撑蒙脱石对罗丹明B的吸附性能[J].四川建材学院学报,2011(4):18-22.
作者姓名:何正先  张宝述  彭同江  孙红娟  董发勤  宋绵新
作者单位:[1]西南科技大学四川省非金属复合与功能材料重点实验室,四川绵阳621010 [2]西南科技大学矿物材料与应用研究所,四川绵阳621010
基金项目:国家自然科学基金(41072033).
摘    要:采用酸性溶胶法制备了钛柱撑蒙脱石,研究了不同温度、pH值条件下样品对罗丹明B的吸附性能。结果表明,钛柱撑可以提高蒙脱石对水溶液中罗丹明B染料的吸附能力,吸附过程动力学符合准二级近似,为不可逆化学吸附,平衡吸附数据基本符合Langmuir和Freundlich吸附等温式;随着温度升高和pH值增大,钛柱撑蒙脱石对罗丹明B的吸附量下降,在温度298K左右,pH值低于3时吸附效果较好。

关 键 词:钛柱撑蒙脱石  罗丹明B  化学吸附  动力学

Study on Rhodamine B Adsorption onto Titanium Pillared Montmorillonite
Authors:HE Zheng-xian  ZHANG Bao-shu    PENG Tong-jiang  SUN Hong-juan  DONG Fa-qin  SONG Mian-xin
Affiliation:2 ( 1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China ; 2. Research Institute of Mineral Materials and Application, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China)
Abstract:The adsorption of rhodamine B onto titanium pillared montmorillonite prepared by sol-acid method has been studied at different temperature and pH. The results indicate that the titanium pillaring can enhance the adsorption performance of rhodamine B in solution by montmorillonite. The adsorption kinetics, which followed pseudo-second order approximate model, is irreversible. The equilibrium adsorption data can better fit with both Langmuir and Freundlich adsorption isothermal equation. The adsorption capacity of rhodamine B onto titanium pillared montmorillonite decreases with the increasing of temperature and pH. The adsorption effect is better at temperature about 298 K and below pH 3.
Keywords:Titanium pillared montmorillonite  Rhodamine B  Adsorption isotherm  Kinetics
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