Relationships between Tg and cohesive energy: 1. Dependence of Tg on the composition of copolymers |
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Authors: | K Marcinčin A Romanov |
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Affiliation: | Polymer Institute of the Slovak Academy of Sciences, Dúbravská cesta, 809 34 Bratislava, Czechoslovakia |
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Abstract: | The possibility of expressing the glass transition temperature of copolymers and homopolymers with an n-alkyl side chain as a function of two parameters (cohesive energy and steric factor) is discussed. An empirical equation representing these two factors is proposed. Calculated values are in good agreement with literature data for the investigated systems. |
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