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A dilatometric study of the solubility of U4O9 in UO2
Authors:M.J. Bannister  W.J. Buykx
Affiliation:Materials Division, AAEC Research Establishment, Lucas Heights, N.S.W., Australia
Abstract:Phase relationships in the system UO2-O9 were studied using a dilatometei in which the O/U ratio of a UU2+x specimen could be both controlled and measured. Phase boundary temperatures were indicated by changes in expansion or contraction rate during heating or cooling, respectively. The solubility of U4O9 in UO2 agreed with the results of previous workers using other techniques. The dependence of solubility on temperature is complex, and appears to be influenced by a high-temperature phase transition in U409.
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