| 笼型六面体倍半硅氧烷衍生物制备聚合物纳米复合材料 |
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| 引用本文： | 张亚峰,孙陆逸,刘安华,龚克成. 笼型六面体倍半硅氧烷衍生物制备聚合物纳米复合材料[J]. 化学世界, 2001, 42(2): 98-102 |
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| 作者姓名： | 张亚峰 孙陆逸 刘安华 龚克成 |
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| 作者单位： | 华南理工大学高聚物结构与改性研究室, |
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| 基金项目： | 国家自然科学基金!资助项目 (2 99740 0 9) |
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| 摘 要： | 笼型六面体倍半硅氧烷 (T8)是一类每个面都由硅氧八元环构成的六面体 ,从它出发可制得以二氧化硅为核心的大分子单体以及无机 /有机纳米复合材料。在叙述了从不同的前驱体制备功能性的 T8方法基础上 ,介绍了从 T8大分子单体出发制备的无机 /有机聚合物纳米复合材料在光固化树脂、耐热阻燃材料、多孔材料、改性高分子材料等领域的应用。
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| 关 键 词： | 倍半硅氧烷 聚合物纳米复合材料 合成 应用 |
| 文章编号： | 0367-6358(2001)02-0098-05 |
| 修稿时间： | 2000-08-22 |
Polymer Nanocomposites derived from Cage Hexahedral Silsesquioxane |
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| ZHANG Ya-feng,SUN Lu-yi,LIU An-Hua,GONG Ke-Cheng. Polymer Nanocomposites derived from Cage Hexahedral Silsesquioxane[J]. Chemical World, 2001, 42(2): 98-102 |
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| Authors: | ZHANG Ya-feng SUN Lu-yi LIU An-Hua GONG Ke-Cheng |
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| Abstract: | Cage hexahedral silsesquioxane (T 8), an octamer, each of its sides consists of silicon and oxygen ring. From which, many kinds of macromer and related inorganic/organic nanocomposites containing inorganic silicon dioxide core have been prepared. In this paper, different methods to prepare T 8 and related functional compounds are introduced, then the applications of inorganic/organic polymer nanocomposites basing on T 8 and related macromer to the fields such as: photocurable resins, thermal-resistant and flame-retard materials, porous materials, modified polymers, etc. a reviewed. |
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| Keywords: | silsesquioxanes polymer nanocomposites synthesis application |
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