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纳米Al_2O_3/聚酰亚胺复合薄膜的介电与力学性能
引用本文:崔晓萍,朱光明,刘文元.纳米Al_2O_3/聚酰亚胺复合薄膜的介电与力学性能[J].复合材料学报,2016,33(11):2419-2425.
作者姓名:崔晓萍  朱光明  刘文元
作者单位:1. 西北工业大学 应用化学系, 西安 710129; 2. 武警工程大学 装备工程学院, 西安 710086; 3. 西北核技术研究所, 西安 710024
摘    要:采用原位聚合与热亚胺化的方法,成功制备了一系列不同纳米Al_2O_3粒子质量分数的纳米Al_2O_3/聚酰亚胺(PI)复合薄膜。通过SEM、TEM、XRD、FTIR、LCR数字电桥、高压电源及电子万能材料试验机对纳米Al_2O_3/PI复合薄膜的微观结构、介电性能及力学性能进行了表征和测试。结果表明:纳米Al_2O_3粒子在均匀地分散在PI基体中;当纳米Al_2O_3粒子质量分数为8%时,纳米Al_2O_3/PI复合薄膜的击穿强度和拉伸强度均达到了最大值;纳米Al_2O_3/PI复合薄膜的介电常数随纳米Al_2O_3质量分数的增加而增加。

关 键 词:聚酰亚胺  纳米Al2O3  复合薄膜  微观结构  介电性能  力学性能  
收稿时间:2015-11-04

Dielectric and mechanical properties of nano Al2O3/polyimide composite films
CUI Xiaoping,ZHU Guangming,LIU Wenyuan.Dielectric and mechanical properties of nano Al2O3/polyimide composite films[J].Acta Materiae Compositae Sinica,2016,33(11):2419-2425.
Authors:CUI Xiaoping  ZHU Guangming  LIU Wenyuan
Affiliation:1. Department of Applied Chemistry, Northwestern Polytechnical University, Xi'an 710129, China; 2. Equipment and Engineering College, Engineering University of Armed Police Force, Xi'an 710086, China; 3. Northwest Institute of Nuclear Technology, Xi'an 710024, China
Abstract:A series of nano Al2O3/polyimide (Al2O3/PI) composite films with different mass fraction of nano Al2O3 particles were successfully prepared via in situ polymerisation and thermal imidization method. The microstructure, dielectric property and mechanical property of nano Al2O3/PI composite films were characterized and measured by SEM, TEM, XRD, FTIR, LCR meter, high voltage power and the electronic universal material testing machine. The results show that nano Al2O3 particles disperse evenly in the PI matrix. The breakdown strength and tensile strength of nano Al2O3/PI composite films both reach a maximum value with nano Al2O3 particles mass fraction of 8%. The dielectric constants of nano Al2O3/PI composite films increase with the increasing of mass fraction for nano Al2O3.
Keywords:polyimide  nano Al2O3  composite film  microstructure  dielectric property  mechanical property
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