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3D成型SiO_2/PVA水凝胶支架的摩擦行为
引用本文:李坚,李学锋,龙世军,李晗,黄大华. 3D成型SiO_2/PVA水凝胶支架的摩擦行为[J]. 复合材料学报, 2016, 33(11): 2412-2418. DOI: 10.13801/j.cnki.fhclxb.20160126.002
作者姓名:李坚  李学锋  龙世军  李晗  黄大华
作者单位:1. 湖北工业大学 材料科学与工程学院, 武汉 430068;2. 湖北工业大学 绿色轻质材料与加工协同创新中心, 武汉 430068;3. 湖北工业大学 绿色轻工材料湖北省重点实验室, 武汉 430068
基金项目:国家自然科学基金(51273059),清华大学摩擦学国家重点实验室开放基金(SKLTKF 14A09)
摘    要:利用3D成型技术,通过先成型后冷冻交联2步法制备不同孔隙率的SiO_2/聚乙烯醇(PVA)水凝胶支架,研究了SiO_2/PVA水凝胶支架的重复摩擦行为,分析了SiO_2/PVA水凝胶支架的摩擦原理。结果表明:SiO_2/PVA水凝胶支架能够保持三维贯通的立体结构,最大孔隙率可达42.3%。低摩擦速率(10-6~10-3 m/s)下,SiO_2/PVA水凝胶支架摩擦力稍高于块体SiO_2/PVA水凝胶,且随孔隙率的提高而稍有降低;而高摩擦速率(10-2~1m/s)下,SiO_2/PVA水凝胶支架和块体SiO_2/PVA水凝胶的摩擦力相近,孔隙率对支架摩擦力影响不明显。低正压力载荷(0.3kPa)下,SiO_2/PVA水凝胶支架重复摩擦性优于块体SiO_2/PVA水凝胶,这与支架结构能保持稳定的水润滑层相关。

关 键 词:聚乙烯醇  水凝胶  支架  3D成型  摩擦  
收稿时间:2015-11-04

Friction behavior of 3D printing SiO2/PVA hydrogel scaffold
LI Jian,LI Xuefeng,LONG Shijun,LI Han,HUANG Dahua. Friction behavior of 3D printing SiO2/PVA hydrogel scaffold[J]. Acta Materiae Compositae Sinica, 2016, 33(11): 2412-2418. DOI: 10.13801/j.cnki.fhclxb.20160126.002
Authors:LI Jian  LI Xuefeng  LONG Shijun  LI Han  HUANG Dahua
Affiliation:1. School of Materials Science and Engineering, Hubei University of Technology, Wuhan 430068, China;2. Collaborative Innovation Center of Green Light-weight Materials and Processing, Hubei University of Technology, Wuhan 430068, China;3. Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068, China
Abstract:SiO2/polyvinyl alcohol (PVA) hydrogel scaffold with different porosities was prepared by two-step method of pre forming and post freezing cross-linking using 3D printing technology. The reproducible friction behaviors of SiO2/PVA hydrogel scaffold was researched and the friction principle of SiO2/PVA hydrogel scaffold was analyzed. The results show that SiO2/PVA hydrogel scaffold can keep a three dimensional through structure with maximum porosity of 42.3%. At low friction velocity(10-6-10-3 m/s), the frictional force of SiO2/PVA hydrogel scaffold is slightly higher than that of bulk SiO2/PVA hydrogel and decreases slightly with the increase of porosity. At high friction velocity(10-2-1 m/s), the frictional force of SiO2/PVA hydrogel scaffold is equal to that of bulk SiO2/PVA hydrogel and the effect of porosity on the frictional force for scaffold is not obvious. At small normal pressure load(0.3 kPa), SiO2/PVA hydrogel scaffold shows better reproducible friction property than bulk SiO2/PVA hydrogel. It is related to the structure of the scaffold which can keep a stable hydrated lubrication layer.
Keywords:polyvinyl alcohol  hydrogel  scaffold  3D printing  friction
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