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Synthesis, electrical and magnetic characterization of core-shell silicon carbo-nitride coated carbon nanotubes
Authors:Gurpreet Singh  Shashank Priya  Maria R. Hossu  Sachit Grover  Roop L. Mahajan
Affiliation:a Institute for Critical Technology and Applied Science (ICTAS), Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA
b Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA
c Department of Physics, University of Texas at Arlington, TX 76019, USA
d Department of Engineering Mechanics, Center for Aircraft Structural Life Extension (CAStLE) United States Air Force Academy, USAF Academy, CO 80840, USA
e Department of Electrical and Computer Engineering, University of Colorado at Boulder, CO 80309, USA
f Department of Mechanical Engineering, Department of Engineering Science and Mechanics, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA
Abstract:We demonstrate synthesis, electrical and magnetic characterization of silicon carbo-nitride (SiCN) coated multiwalled carbon nanotubes in a core-shell structure. The core formed by a carbon nanotube had a diameter in the range of 10-100 nm. The shell was synthesized by pyrolysis of an SiCN precursor on the surface of carbon nanotubes. Electrical resistivity of an individual composite nanotube was measured to be ~ 2.55 × 103 Ω cm. The magnetic measurements performed by a superconducting quantum interference device on the composite nanotubes in the temperature range of 5-300 K show a reduced coercive field with increasing temperatures. The monolayer thick coating of an ultra high temperature multifunctional ceramic SiCN makes these composite nanotubes very promising for sensing applications in harsh environments.
Keywords:SiCN   Carbon nanotubes   Focused ion beam   Magnetization   Nanomanipulation
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