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马来酰亚胺侧基聚酰亚胺薄膜的制备与性能研究
引用本文:虞鑫海,许梅芳,樊良子,徐永芬,陈武荣,李立严.马来酰亚胺侧基聚酰亚胺薄膜的制备与性能研究[J].绝缘材料,2011,44(4):1-3,8.
作者姓名:虞鑫海  许梅芳  樊良子  徐永芬  陈武荣  李立严
作者单位:1. 东华大学应用化学系,上海,201620
2. 桂林电器科学研究院,广西桂林,541004
基金项目:上海市博士后重点重大项目(09R21421000)
摘    要:利用2,2-双4-(2,4-二氨基苯氧基)苯基]丙烷(BDAPPP)单体、马来酸酐(MA)、4,4’-二氨基二苯醚( 44ODA)及3,3’,4,4’-四羧酸联苯二酐(BPDA)合成制得马来酰胺酸侧基的聚酰胺酸树脂(MPAA)溶液,经涂膜,热亚胺化,得到坚韧透明的马来酰亚胺侧基聚酰亚胺薄膜(MPI),并对其性能进行研...

关 键 词:2  2-双[4-(2  4-二氨基苯氧基)苯基]丙烷  马来酰亚胺侧基聚酰亚胺  薄膜

Preparation and Properties of Novel Polyimide Film with Maleimide Side Groups
Yu Xinhai,Xu Meifang,Fan Liangzi,Xu Yongfen,Chen Wurong,Li liyan.Preparation and Properties of Novel Polyimide Film with Maleimide Side Groups[J].Insulating Materials,2011,44(4):1-3,8.
Authors:Yu Xinhai  Xu Meifang  Fan Liangzi  Xu Yongfen  Chen Wurong  Li liyan
Affiliation:Yu Xinhai1,Xu Meifang1,Fan Liangzi1,Xu Yongfen1,Chen Wurong2,Li liyan2(1.Department of Applied Chemistry,Donghua University,Shanghai 201620,China,2.Guilin Electrical Equipment Scientific Research Institute,Guilin 541004,China)
Abstract:Based on the monomers of 2,2-bis4-(2,4-diaminophenoxy)phenyl]propane(BDAPPP),maleic anhydride(MA),4,4'-diaminodiphenyl ether(44ODA) and 3,3',4,4'-tetracarboxylbiphenyl dianhydride(BPDA),a novel polyamic acid solution with maleimide side groups(MPAA) was synthesized.The transparent and tenacious polyimide film with maleimide side groups(MPI) was prepared through imidized process of the MPAA thin layer,and then the properties of the MPI were studied.The results show that the MPI has low surface energy(34.4 m...
Keywords:2  2-bis[4-(2  4-diaminophenoxy)phenyl]propane  polyimide with maleimide side groups  film  
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