| 磷改性对ZSM-5分子筛石脑油催化裂解性能的影响 |
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| 引用本文： | 鄢德怀,关毅达,张晶晶. 磷改性对ZSM-5分子筛石脑油催化裂解性能的影响[J]. 当代化工, 2011, 40(8): 784-786 |
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| 作者姓名： | 鄢德怀 关毅达 张晶晶 |
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| 作者单位： | 中国石油抚顺石化分公司,辽宁抚顺,113008;中国石化燕山石化分公司化工一厂,北京,102500 |
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| 摘 要： | 以HZSM-5分子筛为载体,以磷酸氢二铵为磷源,采用等体积浸渍法制备了磷改性ZSM-5分子筛,采用吡啶吸附红外光谱法研究了磷改性ZSM-5分子筛的酸性及水热稳定性,在小型固定床反应装置上进行了石脑油催化裂解反应研究.结果表明,适量磷(3％)改性显著改善了ZSM-5分子筛的酸性和水热稳定性,提高了ZSM-5分子筛催化剂的...
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| 关 键 词： | 磷 ZSM-5分子筛 石脑油 催化裂解 丙烯 |
Influence of Phosphorus Modification on Acidity and Performance of ZSM-5 Zeolite for Naphtha Catalytic Cracking |
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| YAN De-huai,GUAN Yi-da,ZHANG Jing-jing. Influence of Phosphorus Modification on Acidity and Performance of ZSM-5 Zeolite for Naphtha Catalytic Cracking[J]. Contemporary Chemical Industry, 2011, 40(8): 784-786 |
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| Authors: | YAN De-huai GUAN Yi-da ZHANG Jing-jing |
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| Affiliation: | YAN De-huai1,GUAN Yi-da1,ZHANG Jing-jing2 (1.PetroChina Fushun Petrochemical Corporation,Liaoning Fushun 100108,China,2.SINOPEC Yanshan Petrochemical Corporation No.1 Chemical Plant,Beijing 102500,China) |
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| Abstract: | Phosphate modified ZSM-5 zeolites were prepared by incipient-wetness impregnation method with HZSM-5 zeolites as supports and diammonium phosphate as phosphorus source.Acdity and hydrothermal stability of phosphate modified ZSM-5 zeolites were studied by pyridine adsorption Fourier-transform infrared reflectance spectroscopy.The catalytic cracking of naphtha was carried out in a small fixed-bed reactor.The results show that modification with suitable amount of phosphorous(3%) can greatly improve the acidity... |
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| Keywords: | Phosphorus modification ZSM-5 zeolite Naphtha Catalytic cracking Propylene. |
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