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铜与硝酸反应的绿色化设计
引用本文:张玉贞,李先栓. 铜与硝酸反应的绿色化设计[J]. 当代化工, 2011, 0(8): 792-794,797
作者姓名:张玉贞  李先栓
作者单位:中国矿业大学化工学院;宿迁高等师范学校;
摘    要:化学实验教学实现绿色化思想的关键有两点:一是挥发有害物质的化学反应在完全密封状态下进行;二是实验产物的无害化处理.利用U型管巧妙设计,可使铜与浓、稀硝酸反应的毒气实验在密闭环保中进行,同时达到了绿色化尾气处理利用NO与浓HNO3反应,可证明铜与浓硝酸反应为什么生成的是NO2而不是NO,从事实上为学生纠错提供了有力判据.

关 键 词:绿色化学  环保  U型管  尾气处理  原子经济

Green Design on the Reaction of Copper and Nitric Acid
ZHANG Yu-zhen,,LI Xian-shuan. Green Design on the Reaction of Copper and Nitric Acid[J]. Contemporary Chemical Industry, 2011, 0(8): 792-794,797
Authors:ZHANG Yu-zhen    LI Xian-shuan
Affiliation:ZHANG Yu-zhen1,2,LI Xian-shuan 2(1.School of Chemical Engineering,China University of Mining and Technology,Jiangsu Xuzhou 221008,China,2.Suqian Higher Normal School,Jiangsu Suqian 223800,China)
Abstract:To achieve green ideas on chemical experiment teaching has to hold two critical points: One is that chemical reactions of harmful volatile materials must be carried out in completely sealed condition;The other is that products need harmlessly be treated for environment.In this paper,using U pipe,the reaction of copper and concentrated/dilute nitric acid can be guaranteed in sealed surroundings and the tail gas was harmlessly treated.The reaction of nitric oxide and concentrated nitric acid demonstrated that...
Keywords:Green chemistry  Environmental protection  U pipe  Tail gas processing  Atom economy  
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