| 磺化改性石油沥青催化苯酚与叔丁醇的反应 |
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| 引用本文： | 张康龙,祁晓津,刘万毅. 磺化改性石油沥青催化苯酚与叔丁醇的反应[J]. 当代化工, 2011, 40(7): 673-675 |
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| 作者姓名： | 张康龙 祁晓津 刘万毅 |
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| 作者单位： | 1. 中国矿业大学银川学院化工系,宁夏银川,750011
2. 宁夏大学化学化工学院,宁夏银川,750021 |
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| 摘 要： | 以磺化改性石油沥青作为一种新型、廉价高效且对环境友好的固体酸催化剂，催化苯酚与叔丁醇的烷基化反应。考察了其催化活性，并系统的研究了酚醇摩尔比、催化剂用量、反应温度、反应时间诸因素对苯酚转化率、产品选择性和催化剂重复使用性的影响。确定了最佳反应条件为T=70℃，t=360 min，n（TBA）/n（Phen01）=2：1，催化剂用量为0．6g，在此条件下，苯酚的转化率达到75．8％。
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| 关 键 词： | 改性石油沥青 催化 合成 选择性 |
Catalytic Reaction of Phenol and Tert-butanol With Sulfonated Asphalt as Catalyst |
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| ZHANG Kang-long,QI Xiao-jin,LIU Wan-yi. Catalytic Reaction of Phenol and Tert-butanol With Sulfonated Asphalt as Catalyst[J]. Contemporary Chemical Industry, 2011, 40(7): 673-675 |
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| Authors: | ZHANG Kang-long QI Xiao-jin LIU Wan-yi |
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| Affiliation: | ZHANG Kang-long1,QI Xiao-jin1,LIU Wan-yi2(1.Department of Chemical Engineering,China University of Mining and Technology,Ningxia Yinchuan 750011,China,2.College of Chemistry and Chemical Engineering,Ningxia University,Ningxia Yinchuan 750021,China) |
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| Abstract: | Asphalt modified by sulfonation as a new,cheap,efficient and environment-friendly solid acid catalyst was applied in alkylation of phenol and tert-butanol.Catalytic activity was investigated,and effect of phenolic/alcohol molar ratio,catalyst amount,reaction temperature,reaction time,etc.on phenol conversion,product selectivity and reusability of the catalyst was studied.The optimum reaction conditions were determined as follows： T = 70 ℃,t = 360 min,n（TBA）/ n（Phenol）=2︰1,catalyst dosage 0.6 g.Under these conditions,phenol conversion rate can reach 75.8%. |
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| Keywords: | Modified asphalt Catalysis Synthesis Selectivity |
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