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非均相共沸精馏分离乙二醇及1,2一丙二醇的研究
引用本文:牛玉锋,刘振华,乔凯,陈明. 非均相共沸精馏分离乙二醇及1,2一丙二醇的研究[J]. 当代化工, 2011, 40(6): 560-561,564
作者姓名:牛玉锋  刘振华  乔凯  陈明
作者单位:1. 辽宁石油化工大学石化学院,辽宁抚顺,113001
2. 抚顺石油化工研究院生物化工部,辽宁抚顺,113001
摘    要:由于乙二醇及1,2一丙二醇的沸点相近,采用常规精馏方法难以分离。本文通过非均相共沸精馏的方法采用乙苯、混合二甲苯、异丙苯三种共沸剂进行实验,结合共沸剂的选择性和共沸物的共沸点来确定共沸剂。通过实验结果分析发现混合二甲苯能明显提高乙二醇及1,2一丙二醇的挥发度,是分离乙二醇及l,2一丙二醇良好的共沸剂。

关 键 词:非均相共沸精馏  共沸剂  乙二醇  1,2-丙二醇

Study on Separation of Glycol and 1,2-Propanediol With Heterogeneous Azeotropic Distillation
NIU Yu-feng,LIU Zhen-hua,QIAO Kai,CHEN Ming. Study on Separation of Glycol and 1,2-Propanediol With Heterogeneous Azeotropic Distillation[J]. Contemporary Chemical Industry, 2011, 40(6): 560-561,564
Authors:NIU Yu-feng  LIU Zhen-hua  QIAO Kai  CHEN Ming
Affiliation:NIU Yu-feng1,LIU Zhen-hua2,QIAO Kai2,CHEN Ming2(1.School of Petrochemical Engineering,Lioaning Shihua University,Liaoning Fushun 113001,China,2.Fushun Research Institute of Petroleum and Petrochemicals,China)
Abstract:It is difficult to separate glycol and 1,2-propanediol with conventional distillation methods because they have similar boiling point.In this paper,the heterogeneous azeotropic distillation was used to separate glycol and 1,2-propanediol with ethylbenzene,mixed xylene and cumene as azeotropic agent,respectively.Combining with the selectivity of azeotropic agent and the azeotropic point of azeotropic agent,suitable azeotropic agent was determined.The experiment results show that the mixed xylene is a good en...
Keywords:Heterogeneous azeotropic distillation  Entrainer  Glycol  1  2-propanediol  
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