| Fe-ZSM-5分子筛上N2O一步氧化苯制苯酚工艺条件研究 |
| |
| 引用本文： | 范卓,李建伟,米冠杰,陈标华.Fe-ZSM-5分子筛上N2O一步氧化苯制苯酚工艺条件研究[J].石油炼制与化工,2009,40(10):30-33. |
| |
| 作者姓名： | 范卓 李建伟 米冠杰 陈标华 |
| |
| 作者单位： | 北京化工大学化工资源有效利用国家重点实验室 北京化工大学化工资源有效利用国家重点实验室 北京化工大学化工资源有效利用国家重点实验室 北京化工大学化工资源有效利用国家重点实验室 |
| |
| 基金项目： | 国家杰出青年科学基金 |
| |
| 摘 要： | 对Fe-ZSM-5分子筛催化剂上N2O一步氧化苯制苯酚的工艺条件进行了实验研究。以单因素实验法系统考察了温度、苯与N2O摩尔比和空速对氧化过程的影响；并基于L16（45）正交实验设计确定相对适宜的氧化工艺条件为：温度400℃、苯与N2O摩尔比5.0∶1、空速6000h-1，在此条件下苯酚收率为45.28％，N2O转化率为89.28%，苯酚选择性为50.72%。
|
| 关 键 词： | 苯 N2O 苯酚 Fe-ZSM-5分子筛 氧化 |
| 收稿时间： | 2009-2-19 |
STUDY ON THE PROCESS CONDITIONS OF BENZENE TO PHENOL BY ONE-STEP OXIDATION WITH NITROUS OXIDE OVER Fe-ZSM-5 ZEOLITE |
| |
| Fan Zhuo,Li Jianwei,Mi Guanjie,Chen Biaohua.STUDY ON THE PROCESS CONDITIONS OF BENZENE TO PHENOL BY ONE-STEP OXIDATION WITH NITROUS OXIDE OVER Fe-ZSM-5 ZEOLITE[J].Petroleum Processing and Petrochemicals,2009,40(10):30-33. |
| |
| Authors: | Fan Zhuo Li Jianwei Mi Guanjie Chen Biaohua |
| |
| Abstract: | The process conditions of benzene to phenol with nitrous oxide over Fe-ZSM-5 zeolite catalyst were studied in this paper.The effects of reaction temperature,C_6H_6/N_2O molar ratio and space velocity on the oxidation process were investigated by single-factor test method,and the optimum process conditions were obtained by means of orthogonal test designed method.Under the optimum conditions of a reaction temperature of 400℃,a C_6H_6/N_2O molar ratio of 5,a space velocity of 6 000 h~(-1),the N_2O conversion,the yield and selectivity of phenol were 89.28%,45.28%and 50.72%,respectively. |
| |
| Keywords: | benzene N2O phenol Fe-ZSM-5 zeolite oxidation |
| 本文献已被 万方数据 等数据库收录！ |
| 点击此处可从《石油炼制与化工》浏览原始摘要信息 |
|
点击此处可从《石油炼制与化工》下载全文 |
