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氟硅橡胶复合膜透气性的研究
引用本文:禚莉,徐燕芳,韩毓旺,俞斌.氟硅橡胶复合膜透气性的研究[J].膜科学与技术,2009,29(2).
作者姓名:禚莉  徐燕芳  韩毓旺  俞斌
作者单位:南京工业大学理学院,南京,210009
摘    要:通过把氟硅橡胶填充进多孔微滤支撑体来制备聚偏氟乙烯(PVDF)和氟硅橡胶(FVMQ)的复合膜.并研究了支撑层孔径和白炭黑填料对FVMQ复合膜透气性能的影响.自制气室,测试了FVMQ复合膜对H2、Ar和N2的渗透特性.结果表明,PVDF膜孔径越大FVMQ复合膜的渗透速率就越快,在FVMQ溶液中加入白炭黑填料却降低了膜的渗透速率.支撑层孔径对膜渗透性能的影响比填料的影响显著.对FVMQ复合膜透气性的研究为其在气体分离方面应用奠定基础.

关 键 词:氟硅橡胶  白炭黑填料  硫化剂  透气率  支撑层  复合膜

Research on permeability of FVMQ composite membranes
ZHUO Li,XU Yanfang,HAN Yuwang,YU Bin.Research on permeability of FVMQ composite membranes[J].Membrane Science and Technology,2009,29(2).
Authors:ZHUO Li  XU Yanfang  HAN Yuwang  YU Bin
Affiliation:College of Sciences;Nanjing University of Technology;Nanjing 210009;China
Abstract:Composite membranes of polyvinylidene fluoride (PVDF) and fluorosilicone elastomer were prepared by filling fluorosilicone gum into porous microfiltration substrate. The effect of support layer's pore size and the fumed silica filler on FVMQ composite membranes' permeability for H2,Ar and N2 were studied. Gas permeation tests were conducted in a lab-constructed chamber cell. The results showed that the greater the pore size, the more rapid the gas permeation speed through FVMQ composite membranes. The perme...
Keywords:FVMQ  fumed silica filler  curing agent  permeability  support layer  composite membrane  
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