Strategic Shuffling of Clay Layers to Imbue Them with Responsiveness |
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Authors: | Raj Kumar Gogoi Kalyan Raidongia |
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Affiliation: | Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, Assam, India |
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Abstract: | Layers of naturally occurring clay minerals are rearranged to prepare highly sensitive multiresponsive clay–clay bilayer membrane (CCBM). The CCBM introduced here responds to the minuscule changes in the surrounding environments including temperature, humidity, and presence of solvent vapors by morphing in specific manners. Strips cut from CCBM exhibit up to 588 N kg?1 force output when exposed to temperature fluctuations. Inheriting the natural stability of clay minerals, CCBM demonstrates extreme robustness, heating up to 500 °C, cooling with liquid N2 and exposure to corrosive chemical vapors did not deteriorate its bending performance. Mechanistic studies suggest that shape transformations of CCBM are driven by the unequal response of its components to external stimuli. |
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Keywords: | clay– clay bilayer membranes montmorillonite reconstructed 2D materials responsive materials vermiculite |
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