Magnetic Susceptibility Study of Sub‐Pico‐emu Sample Using a Micromagnetometer: An Investigation through Bistable Spin‐Crossover Materials |
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Authors: | Souleymane Kamara Quang‐Hung Tran Vincent Davesne Gautier Félix Lionel Salmon Kunwoo Kim CheolGi Kim Azzedine Bousseksou Ferial Terki |
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Affiliation: | 1. Institut Charles Gerhardt de Montpellier UMR 5253, Université de Montpellier, Montpellier Cedex 5, France;2. Laboratoire de Chimie de Coordination UPR 8241, CNRS, Toulouse Cedex 4, France;3. Department of Emerging Materials Science, DGIST – Deagu Gyeongbuk Institute of Science and Technology, Deagu, Korea |
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Abstract: | A promising and original method to study the spin‐transition in bistable spin‐crossover (SCO) materials using a magnetoresistive multiring sensor and its self‐generated magnetic field is reported. Qualitative and quantitative studies are carried out combining theoretical and experimental approaches. The results show that only a small part of matter dropped on the sensor surface is probed by the device. At a low bias‐current range, the number of detected nanoparticles depends on the amplitude of the current. However, in agreement with the theoretical model, the stray voltage from the particles is proportional to the current squared. By changing both the bias current and the concentration of particle droplet, the thermal hysteresis of an ultrasmall volume, 1 × 10?4 mm3, of SCO particles is measured. The local probe of the experimental setup allows a highest resolution of 4 × 10?14 emu to be reached, which is never achieved by experimental methods at room temperature. |
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Keywords: | magnetic susceptibility magneto‐resistive sensors self‐magnetic field spin‐crossover |
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