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Roll‐to‐Roll Production of Transparent Silver‐Nanofiber‐Network Electrodes for Flexible Electrochromic Smart Windows
Authors:Sen Lin  Xiaopeng Bai  Haiyang Wang  Haolun Wang  Jianan Song  Kai Huang  Chang Wang  Ning Wang  Bo Li  Ming Lei  Hui Wu
Affiliation:1. State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing, China;2. State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, China;3. Advanced Materials Institute, Shenzhen Graduate School, Tsinghua University, Shenzhen, China;4. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, China
Abstract:Electrochromic smart windows (ECSWs) are considered as the most promising alternative to traditional dimming devices. However, the electrode technology in ECSWs remains stagnant, wherein inflexible indium tin oxide and fluorine‐doped tin oxide are the main materials being used. Although various complicated production methods, such as high‐temperature calcination and sputtering, have been reported, the mass production of flexible and transparent electrodes remains challenging. Here, a nonheated roll‐to‐roll process is developed for the continuous production of flexible, extralarge, and transparent silver nanofiber (AgNF) network electrodes. The optical and mechanical properties, as well as the electrical conductivity of these products (i.e., 12 Ω sq?1 at 95% transmittance) are comparable with those AgNF networks produced via high‐temperature sintering. Moreover, the as‐prepared AgNF network is successfully assembled into an A4‐sized ECSW with short switching time, good coloration efficiency, and flexibility.
Keywords:Ag nanofibers  electrochromic smart windows  flexible electronics  roll‐to‐roll
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