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不同粒度煤粉对Ni2+的吸附特性
引用本文:刘转年,周安宁,金奇庭.不同粒度煤粉对Ni2+的吸附特性[J].煤炭学报,2005,30(5):627-631.
作者姓名:刘转年  周安宁  金奇庭
作者单位:西安科技大学 地质与环境工程系,陕西 西安 710054
基金项目:陕西省自然科学基金资助项目(2001C37).
摘    要:通过筛分和高能球磨得到不同粒度的煤粉,研究了粒度变化对水溶液中Ni2+的吸附性能的影响和吸附机理.结果表明:不同粒度煤粉对Ni2+的吸附符合二级吸附动力学,其吸附过程由孔隙内扩散控制,求出了有效扩散系数.得出不同粒度煤粉对Ni2+的吸附量随粒径的减小呈指数关系增加;粒径为9.30,4.28和4.82 μm煤粉对Ni2+的吸附符合Freundlich吸附等温式.

关 键 词:不同粒度煤粉  Ni2+  吸附特性
文章编号:0253-9993(2005)05-0627-05
收稿时间:2004-12-29
修稿时间:2004年12月29

Adsorption properties of Ni2+for different granularity coal powders
LIU Zhuan-nian,ZHOU An-ning,JIN Qi-ting.Adsorption properties of Ni2+for different granularity coal powders[J].Journal of China Coal Society,2005,30(5):627-631.
Authors:LIU Zhuan-nian  ZHOU An-ning  JIN Qi-ting
Affiliation:LIU Zhuan-nian~
Abstract:Different granularity coal powders were obtained by sieving and high energy ball milling,the adsorption mechanism and effect of granularity variety on Ni2+ adsorption were studied.The result shows that the kinetic of Ni2+ for coal powders fit second order kinetic model, the adsorption process is controlled by pore diffusion, the effective diffusion coefficient were calculated.Ni2+ adsorption capacity exponentially increased when coal powders diameter decreased.The Ni2+ adsorption equilibrium of diameter 9.30,4.28 and 4.82 μm coal powders can be described in terms of Freundlich isotherm.
Keywords:different granularity coal powders  Ni~(2+)  adsorption properties  
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