Preparation and the catalytic activity of novel Pd nanocluster catalysts utilizing an oligosilsesquioxane ligand |
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| Authors: | Kenji Wada Kousuke Yano Teruyuki Kondo Take-aki Mitsudo |
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| Affiliation: | (1) Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 615-8510, Japan |
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| Abstract: | Palladium acetate together with a newly synthesized silsesquioxane- pyridyl ligand showed excellent catalytic activity towards
the aerobic oxidation of benzyl alcohol to benzaldehyde. TEM measurements revealed the in situ formation of Pd nanoclusters during the reaction period. |
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| Keywords: | silsesquioxane pyridyl ligand palladium nanoclusters aerobic oxidation benzyl alcohol |
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