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载银二氧化钛光催化性能的研究
引用本文:张海禄,童仕唐,吴省. 载银二氧化钛光催化性能的研究[J]. 应用化工, 2003, 32(2): 20-22
作者姓名:张海禄  童仕唐  吴省
作者单位:武汉科技大学,化工与资源环境学院,湖北,武汉,430081
基金项目:湖北省教育厅重点科研计划项目(2002A000109).
摘    要:考察了用Ag2CO3法制备的载银二氧化钛对十二烷基苯磺酸钠(SDBS)降解反应催化活性的差异。结果表明,与未改性样品比较,载银TiO2的光催化活性得到了明显提高,最佳载银量约为5%。载银TiO2经红外干燥,催化活性进一步提高且最佳载银量变化为10%。对载银TiO2进行超声波震荡处理,催化活性也可以显著提高。经红外干燥处理载银10%TiO2对SDBS的4h和5h催化降解率分别达到了80.40%和89.57%,为本试验中最佳催化剂。

关 键 词:TiO2  光催化活性  表面改性  污水处理
文章编号:1671-3206(2003)02-0020-03
修稿时间:2002-11-05

Study on photocatalytic properties of TiO2-carring silver
Abstract:The distinction of photocatalytic activity of degradating sodium dodecyl benzene sulfonate(SDBS) is tested by TiO2 carring silver (Ag TiO2) prepared from Ag2CO3.The results showed that, compared with the untreated sample, Ag TiO2 exhibits higher photocatalytic activity, the optimal quantity of Ag is about 5%. Ag TiO2 treaded by infrared ray shows a further photocatalytic activity and the optimal quantity of Ag changes to 10%. Ag TiO2 is treaded by ultrasonic wave, the catalysis activity can be improved notably too. Using 10%Ag TiO2 treaded by infrared ray, the degradation velocity of SDBS reached 80.40% and 89.57% respectively after 4 h and 5 h,it is the best catalyst in this experiment.
Keywords:TiO_2  photocatalytic activity  surface modification  waste water treatment
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