Electrochemical Reduction of 2,4-Dinitrotoluene in a Continuous Flow Laboratory Scale Reactor |
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Authors: | Rajesh B. Doppalapudi George A. Sorial Stephen W. Maloney |
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Affiliation: | 1Graduate Student, Dept. of Civil and Environmental Engineering, Univ. of Cincinnati, Cincinnati, OH 45221-0071. 2Associate Professor, Dept. of Civil and Environmental Engineering, Univ. of Cincinnati, 741 Baldwin Hall, P.O. Box 210071, Cincinnati, OH 45221-0071 (corresponding author). 3Engineer, U.S. Army Corps of Engineers, Construction Engineering Research Laboratory, Champaign, IL 61824.
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Abstract: | An electrochemical laboratory scale reactor was used to treat 2,4-dinitrotoluene (DNT). Experiments were conducted by using a graphite carbon cylinder impregnated with glassy carbon (zero porosity) as the cathode and a platinum wire as the anode. All experiments were conducted under anoxic conditions. Initially, experiments simulating batch conditions were conducted to obtain the optimum operating conditions for the reactor. During this batch-mode study, the effect of various parameters such as applied current, electrolyte concentration, and type of electrolyte on the reduction of DNT were evaluated. Results showed that the rates of DNT reduction increased with an increase in current or concentration of electrolyte. Based on the results obtained from the batch simulation experiments, continuous flow experiments were conducted at three different currents and one electrolyte concentration. The ionic strength of the feed solution was maintained at 0.027 M. A current of 200 mA (current density 0.088 mA/cm2) provided a stable reduction of DNT at the 80% level for a period of 14 days after which reactor cleaning was necessary for removal of suspended solids that were formed within the reactor. End products determined for the experiments showed 80–100% molar balance closure. |
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Keywords: | Cisterns Laboratory tests Wastewater treatment |
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