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Supported Vanadia Catalysts for Dehydrogenation of Ethylbenzene with CO2
Authors:Xiao-Hong Li  Wen-Ying Li  Ke-Chang Xie
Affiliation:(1) Key Laboratory of Coal Science and Technology for Ministry of Education and Shanxi Province, Taiyuan University of Technology, No. 79 Yingze West Street, Taiyuan, 030024, P.R. China
Abstract:Alumina supported vanadia catalysts (V/Al) for selective oxidehydrogenation of ethylbenzene with CO2 were prepared by impregnation method. During preparation the effect of promoters and calcined temperature was investigated, it was found these two items had a strong influence on the activity of V/Al catalysts. Dehydrogenation reaction with CO2 was happened in the fixed-bed reactor at 450 °C. Results showed that 15.2% ethylbenzene conversion and 99.2% styrene selectivity were acquired when V2K/Al catalyst was used.
Keywords:dehydrogenation  ethylbenzene  styrene  carbon dioxide  supported catalyst
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