Electronic properties of 1,3,5-tris[4-morpholinophenyl]benzene: a new molecular switch |
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| Affiliation: | 1. Synthèse Organique et Réactivité, UMR CNRS 7565, Université Henri Poincaré, Nancy I, Faculté des Sciences, BP 239, Vandoeuvre les Nancy Cedex 54506, France;2. Laboratoire de Chimie Physique et Microbiologie pour l’Environnement, UMR 7564, CNRS-Université Henri Poincaré, Nancy I, 405, rue de Vandoeuvre, Villers-les-Nancy 54600, France;1. Beijing University of Chinese Medicine, Beijing 100029, China;2. Second Department of TCM Pulmonary Disease, The Key Institute of State Administration of Traditional Chinese Medicine (pneumonopathy chronic cough and dyspnea), Beijing Key Laboratory (NO. BZ0321), China-Japan Friendship Hospital, Beijing 100029, China;3. State Key Laboratory for Infectious Diseases Prevention and Control, and National Institute for Communicable Disease Control and Prevention, Beijing 102206, China;4. Chinese Center for Disease Control and Prevention. Collaborative Innovation Center Diagnosis and Treatment of Infectious Disease, Hangzhou 310003, Zhejiang, China;5. Institute of Infectious Diseases, Beijing Ditan Hospital, Capital Medical University, Beijing Key Laboratory of Emerging Infectious Diseases, Beijing 100015, China;6. Nephrology Department, Aviation General Hospital of China Medical University, Beijing 100012, China |
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| Abstract: | A new electron-donor, 1,3,5-tris4-morpholinophenyl]benzene 1, was synthetised via nickel-catalysed arylamination reactions and characterised by cyclic voltammetry. It was found that electrochemical or chemical oxidation of 1 generates mono- or di(cation radical)s that are stable over 30 min at room temperature. |
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