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Exhaustive removal of anions from aqueous waste via nucleophilic displacement reactions in the presence of phase transfer catalysts
Affiliation:1. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India;2. Center for Environment and Water, The Research Institute, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia;1. Department of Materials Science and Engineering, and Research Institute of Advanced Materials, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul, 08826, Republic of Korea;2. Department of Organic Materials and Fiber Engineering, Soongsil University, 369 Sangdo-ro, Dongjak-gu, Seoul, 06978, Republic of Korea;1. Graduate School of Mathematical Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8914, Japan;2. University of Science, Vietnam National University, Ha Noi, Viet Nam;3. Institute of Mathematics, Vietnam Academy of Science and Technology, Ha Noi, Viet Nam;4. Department of Mathematics, FPT University, Ha Noi, Viet Nam;5. Institute of Research and Development, Duy Tan University, Da Nang, Viet Nam;6. Faculty of Natural Sciences, Duy Tan University, Da Nang, Viet Nam;7. Center for Partial Differential Equations, School of Mathematical Sciences and Shanghai Key Laboratory of PMMP, East China Normal University, Shanghai 200062, China;8. IECL, UMR 7502, Université de Lorraine, 57073 Metz, France
Abstract:Nucleophilic anions such as phenoxide and cyanide dissolved in an aqueous phase were effectively reacted with alkyl halides present in an organic phase containing a phase transfer catalyst. Preliminary data show the concentration of these anions in water decreased from 10,000 ppm to less than 1 ppm in 2–3 h at less than 70 °C. This methodology enables treatment of hazardous anions that are difficult to remove when using a conventional approach.
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