Supported organometallic complexes. Part 37: synthesis and structures of diamine-bis(methoxyethyldimethylphosphine)ruthenium(II) complexes |
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| Affiliation: | 1. School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran;2. Materials Chemistry Research Center, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand |
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| Abstract: | The first two examples of diamineruthenium(II) complexes containing the hemilabile methoxyethyldimethylphosphine ligand, Cl2Ru(en)(η1-Me2PCH2CH2OMe)2 (2a) and Cl2Ru(R,R)-dpen](η1-Me2PCH2CH2OMe)2 (2b) (en=1,2-diaminoethane, (R,R)-dpen=1R,2R-1,2-diamino-1,2-diphenylethane) have been synthesized and structurally characterized. |
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