Crystal structure and photo-induced property of two-dimensional silver(I) complex with 1,3,5-tris(benzylsulfanyl)benzene |
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| Affiliation: | 1. Department of Chemistry, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan;2. Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka 577-8502, Japan;1. Henan Key Laboratory of Functional Salt Materials, Center for Advanced Materials Research, Zhongyuan University of Technology, Zhengzhou 450007, China;2. College of Materials Engineering, Henan International Joint Laboratory of Rare Earth Composite Materials, Henan University of Engineering, Zhengzhou 451191, China;3. State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;1. Departament de Química, Universitat Autònoma de Barcelona, 08193-Bellaterra, Barcelona, Spain;2. Departament de Física, Universitat Autònoma de Barcelona, 08193-Bellaterra, Barcelona, Spain;3. Cristal·lografia, Mineralogia i Dipòsits Minerals, Universitat de Barcelona, Martí i Franquès s/n, 08028 Barcelona, Spain;4. Unitat de Difracció de Raig-X, Centres Científics i Tecnològics de la Universitat de Barcelona (CCiTUB), Universitat de Barcelona, Solé i Sabarís, 1-3, 08028 Barcelona, Spain;1. Department of Chemical Engineering, University of Washington, Campus Box 351750, Seattle, WA 98195, USA;2. Elsa Biologics, LLC, Box 25725, WA 98165, USA;1. Institute of Inorganic Chemistry, University of Regensburg, 93040 Regensburg, Germany;2. Institute of Physical Chemistry, University of Münster, 48149 Münster, Germany;3. Institute of Biophysics and Physical Biochemistry, University of Regensburg, 93040 Regensburg, Germany |
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| Abstract: | The silver(I) complex [Ag2(3bsb)2(ClO4)2] (1) (3bsb; 1,3,5-tris(benzylsulfanyl)benzene) has been prepared and its molecular structure was determined by X-ray crystallography. In 1, the silver ion prefers a tetrahedral coordination geometry and produces a two-dimensional sheet structure containing dimeric units. Irradiation of this complex 1 with light changes its color from white to pink; heat or exposure to acetone vapor makes the irradiated sample revert back to white. However, only 3bsb has no characteristic like this photochromism. |
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