(Terpyridine)(acetylacetonate)ruthenium(II) complex with a zwitterionic form of phosphoniophenylcyanamide ligand |
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| Affiliation: | 1. University of Lille, CNRS, UMR 8576, UGSF, Unité de Glycobiologie Structurale et Fonctionnelle, F 59 000 Lille, France;2. Institut National de la Santé et de la Recherche Médicale, Unité Mixte de Recherche 1195, Université Paris XI, Le Kremlin Bicêtre, France;3. Sorbonne Universités, UPMC Univ Paris06, Ecole Normale Supérieure—PSL Research University, CNRS UMR 7203, Laboratoire des Biomolécules, 4, Place Jussieu, 75252 Paris Cedex 05, France;4. CNRS, INSA—Université Paul Sabatier, LISBP UMR5504, Toulouse, France |
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| Abstract: | The complex [Ru(tpy)(acac)(PPh4cyd)][PF6] (where tpy: 2,2′:6′,2″-terpyridine, acac: acetylacetone and PPh4cyd: 4-triphenylphosphoniophenylcyanamide) has been synthesized. It contains the zwitterionic form of the phosphoniophenylcyanamide ligand. Characterizations were carried out using IR, ES-MS, UV–Vis, electrochemistry and 1H, 13C and 31P NMR spectroscopy. |
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