亚磷酸盐臭氧化合物研究新进展

有关亚磷酸盐臭氧化合物的研究一直为人们所关注。这主要有三个方面的原因:(1)它是单重态氧气的重要化学来源,而单重态氧气可以作为氧碘化学激光的储能分子;(2)亚磷酸盐臭氧化合物的结构独特,一直为人们所关注;(3)它们的热分解以及催化分解的具体反应机理还不是很清楚,这也是目前研究的一个热点。本文主要从上述三个方面来综述亚磷酸盐臭氧化合物的相关研究。

New Advances of Phosphite Ozonides

The research on phosphite ozonides has received much attention, There are three primary reasons for this. For one thing, the decomposition of phosphite ozonides has been well recognized as a convenient chemical source of singlet oxygen for the chemical oxygen - iodine laser. For another, the special structures of phosphite ozonides also attracted much attention. For still another, phosphite ozonides have gained much favor because the mechanistic detail of their thermal decomposition and catalyzed -decomposition remains a puzzle. In this paper, we review the research on phosphite ozonides in three aspects mentioned above.