| 3,6-二（3 ′-氨基呋咱-4-基）-1,4-二氧杂-2,5-二氮杂环己-2,5-二烯的晶体结构（英） |
| |
| 引用本文： | 王军,董海山,黄奕刚,李金山.3,6-二（3 ′-氨基呋咱-4-基）-1,4-二氧杂-2,5-二氮杂环己-2,5-二烯的晶体结构（英）[J].含能材料,2006,14(6):446-448. |
| |
| 作者姓名： | 王军 董海山 黄奕刚 李金山 |
| |
| 作者单位： | 中国工程物理研究院化工材料研究所,四川,绵阳,621900 |
| |
| 基金项目： | China Academy of Engineering Physics （ No. 2002Z0501 ） |
| |
| 摘 要： | 制备并表征了化合物3,6-二(3'-氨基呋咱-4-基)-1,4-二氧杂-2,5-二氮杂环己-2,5-二烯(BADDD) .其晶体结构参数为:Mr=252.17,三斜晶系,P-1空间群,a=0.48616 (10) nm,b=0.5237 (2) nm,c=0.97076 (19) nm,α=102.25(3)°,β=93.631(17)°,γ=101.88 (2)°,V=0.23489 (12) nm3,Z=1,Dc=1.783g·cm-3,λ (MoKα)=0.071073 nm,μ(MoKα)=0.153 mm-1,F(000)=128,T=294 (2) k,R1=0.0351 and wR2=0.0875.BADDD分子由两个氨基呋咱环和一个由两个O原子,两个N原子和两个C原子组成的六元杂环构成.分子具有中心对称性.
|
| 关 键 词： | 物理化学 高能化合物 3 6-二(3'-氨基呋咱-4-基)-1 4-二氧杂-2 5-二氮杂环己-2 5-二烯 晶体结构 physical chemistry high energetic compound 3 6-bis (3'-aminofurazan-4-yl) -1 4-dioxa-2 5-diaza-cyclohexa-2 5-diyne (BADDD) crystal structure |
| 文章编号： | 1006-9941（2006）06-0446-03 |
| 收稿时间： | 2006-07-11 |
| 修稿时间： | 2006-09-27 |
Crystal Structure of 3,6-Bis(3'-aminofurazan-4-yl)-1,4-dioxa-2,5-diazacyclohexa-2,5-diyne |
| |
| WANG Jun,DONG Hai-shan,HUANG Yi-gang and LI Jin-shan.Crystal Structure of 3,6-Bis(3''''-aminofurazan-4-yl)-1,4-dioxa-2,5-diazacyclohexa-2,5-diyne[J].Chinese Journal of Energetic Materials,2006,14(6):446-448. |
| |
| Authors: | WANG Jun DONG Hai-shan HUANG Yi-gang and LI Jin-shan |
| |
| Affiliation: | Institute of Chemical Materials, CAEP, Mianyang 621900, China;Institute of Chemical Materials, CAEP, Mianyang 621900, China;Institute of Chemical Materials, CAEP, Mianyang 621900, China;Institute of Chemical Materials, CAEP, Mianyang 621900, China |
| |
| Abstract: | The compound of 3,6-bis(3'-aminofurazan-4-yl)-1,4-dioxa-2,5-diazacyclohexa-2,5-diyne (BADDD) was obtained and characterized. It is triclinic,P-1,and with parameters of a=0.48616 (10) nm,b=0.5237 (2) nm,c=0.97076 (19) nm,α=102.25(3)°,β=93.631(17)°,γ=101.88 (2)°,V=0.23489 (12) nm3,Z=1,Dc=1.783g·cm-3,λ (MoKα)=0.071073 nm,μ(MoKα)=0.153 mm-1,F(000)=128,T=294 (2) k,R1=0.0351 and wR2=0.0875. The molecule consists of two aminofurazano rings and a 6-membered heterocycle formed by two O atoms,two N atoms and two C atoms,respectively. The molecule is centrally symmetrical. |
| |
| Keywords: | physical chemistry high energetic compound 3 6-bis (3'-aminofurazan-4-yl) -1 4-dioxa-2 5-diaza-cyclohexa-2 5-diyne (BADDD) crystal structure |
| 本文献已被 万方数据 等数据库收录！ |
| 点击此处可从《含能材料》浏览原始摘要信息 |
|
点击此处可从《含能材料》下载全文 |
|
