| P(AM-co-AMPS)基凝胶的溶胀动力学研究 |
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| 引用本文： | 李云龙,柯爱茹,欧阳娜,林松柏.P(AM-co-AMPS)基凝胶的溶胀动力学研究[J].材料开发与应用,2010,25(5):60-63,68. |
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| 作者姓名： | 李云龙 柯爱茹 欧阳娜 林松柏 |
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| 作者单位： | 黎明职业大学轻纺系,福建,泉州,362000;黎明职业大学轻纺系,福建,泉州,362000;黎明职业大学轻纺系,福建,泉州,362000;黎明职业大学轻纺系,福建,泉州,362000 |
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| 基金项目： | 福建省教育厅A类项目(JA09274); 泉州市技术研究与开发项目(2009Z60) |
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| 摘 要： | 本文以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为有机单体、正硅酸乙酯(TEOS)为无机原料合成了P(AM-co-AMPS)基水凝胶,研究了凝胶的相转变温度,以及在相转变温度前后的溶胀性能和溶胀动力学。结果表明,P(AM-co-AMPS)凝胶在25℃水温下主要以大分子松弛为主的溶胀方式,而在0℃水温下为Fickian扩散方式,且具有一定的温敏性;P(AM-co-AMPS)/SiO2杂化凝胶在0℃和25℃均保持非Fickian扩散方式,且温敏性被掩盖。
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| 关 键 词： | 杂化凝胶 动力学 互穿网络 |
Study on the Swelling Kinetic of P(AM-co-AMPS)-based Hydrogels |
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| LI Yun-long,KE Ai-ru,OU-YANG Na,LIN Song-bai.Study on the Swelling Kinetic of P(AM-co-AMPS)-based Hydrogels[J].Development and Application of Materials,2010,25(5):60-63,68. |
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| Authors: | LI Yun-long KE Ai-ru OU-YANG Na LIN Song-bai |
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| Affiliation: | LI Yun-long,KE Ai-ru,OU-YANG Na,LIN Song-bai (Dept.of Light-textile Eng.,Liming Voca.Univ.,Quanzhou 362000,China) |
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| Abstract: | In this paper,the hydrogels were prepared with the copolymer of acrylamide（AM） and 2-acrylamide-2-aethylpropanesul-fonic acid（AMPS） as the organic phase,introducing silicon dioxide（SiO2） as inorganic phase which obtained by Ethyl silicate（TEOS）.The phase inversion temperature,swelling behavior and swelling kinetic in water at temperatures（25℃ and 0℃） of the hydrogels were studied.It was showed that P（AM-co-AMPS） hydrogels swelling mechanism belong to macromolecule relaxation at 25℃,but belong to Fickian diffusion at 0℃ yet,indicating that they are temperature-sensitive,while P（AM-co-AMPS）/SiO2 hybrid hydrogels swelling mechanism all belongs to non-Fickian diffusion at 25℃ and 0℃,and the temperature-sensitive of these hybrid hydrogels are vanished. |
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| Keywords: | Hybrid hydrogels Kinetic Interpenetrating network |
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