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溶胶-凝胶法制备铜锌锡硫薄膜及其太阳能电池的研究进展
引用本文:高金凤,李明慧,徐键,方刚. 溶胶-凝胶法制备铜锌锡硫薄膜及其太阳能电池的研究进展[J]. 材料导报, 2017, 31(17): 146-151, 157. DOI: 10.11896/j.issn.1005-023X.2017.017.021
作者姓名:高金凤  李明慧  徐键  方刚
作者单位:宁波大学信息科学与工程学院,宁波,315211
基金项目:宁波市自然科学基金(2016A610067);宁波大学王宽诚幸福基金
摘    要:原料丰富价廉的铜锌锡硫(Cu2ZnSnS4,CZTS)材料与非真空、低成本绿色溶胶-凝胶法相结合在产业化制造高性价比CZTS薄膜太阳能电池方面的应用引人关注。为了了解未来发展方向,综述了溶胶-凝胶法制备CZTS薄膜与器件的研究进展,讨论了不同溶胶-凝胶工艺途径、不同溶剂、硫化等对CZTS薄膜制备与器件特性的影响,分析了Na掺杂及硫化退火对CZTS薄膜的作用,并结合绿色制造的要求探讨了其发展趋势。

关 键 词:铜锌锡硫  溶胶-凝胶法  薄膜太阳能电池  绿色制造

Development of Sol-Gel Fabrication of Cu2ZnSnS4 Thin-films and Solar Cells
GAO Jinfeng,LI Minghui,XU Jian and FANG Gang. Development of Sol-Gel Fabrication of Cu2ZnSnS4 Thin-films and Solar Cells[J]. Materials Review, 2017, 31(17): 146-151, 157. DOI: 10.11896/j.issn.1005-023X.2017.017.021
Authors:GAO Jinfeng  LI Minghui  XU Jian  FANG Gang
Affiliation:College of Information Science & Engineering, Ningbo University, Ningbo 315211,College of Information Science & Engineering, Ningbo University, Ningbo 315211,College of Information Science & Engineering, Ningbo University, Ningbo 315211 and College of Information Science & Engineering, Ningbo University, Ningbo 315211
Abstract:The combination of low-cost and abundant Cu2ZnSnS4 (CZTS) material and a low-cost non-vacuum and green sol-gel technique attracts researcher's attention for application in industrialized fabrication of higher performance-price ratio CZTS solar cells.In order to know its future research direction,the development of sol-gel fabrication of CZTS thin films and solar cells has been reviewed.Effects of different preparation conditions such as sol-gel routes,solvents and sulfuration on CZTS thin films and devices are discussed.The effect of Na-doping and sulfuration-annealing on CZTS films are also analyzed.The development trend about green fabrication of CZTS films and devices is discussed.
Keywords:CZTS   sol-gel method   thin-film solar cells   green process
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