An excellent support of Pd–Fe–Ox catalyst for low temperature CO oxidation: CeO2 with rich (200) facets |
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Affiliation: | 1. School of Materials Science and Engineering, Chang’an University, Xi’an 710064, China;2. State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, China;1. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, PR China;2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China;3. Department of Physics and Interdisciplinary Program of Biomedical, Mechanical and Electrical Engineering, Pukyong National University, Busan 608-737, Republic of Korea;1. Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi Sci-Tech University, Hanzhong 723000, PR China;2. Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, PR China |
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Abstract: | Pd–Fe–Ox catalysts for low temperature CO oxidation were supported on SBA-15, CeO2 nano-particles with rich (111) facets and CeO2 nano-rod with rich (200) facets, and characterized by X-ray diffraction, low-temperature nitrogen adsorption, transmission electron microscopy and temperature-programmed reduction. The results showed that when CeO2 nano-rod was used as a support, Pd–Fe–Ox catalyst exhibits higher activity (T100 = 10 °C), resulting from the rich (200) facets of CeO2 nano-rod, which leads to a formation of large numbers of the oxygen vacancies on the surface of Pd–Fe–Ox catalysts. |
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