Novel application of g-C3N4/NaNbO3 composite for photocatalytic selective oxidation of biomass-derived HMF to FFCA under visible light irradiation |
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Affiliation: | 1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China;2. Institute of Chemistry, Technical Chemistry, Carl von Ossietzky University Oldenburg, Carl-von-Ossietzky-Str. 9-11, 26129 Oldenburg, Germany |
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Abstract: | The g-C3N4/NaNbO3 photocatalyst was synthesized by simply calcining the mixture of NaNbO3 and melamine. The synthesized composite exhibits high photocatalytic performance in the selective oxidation of 5-Hydroxymethylfurfural (HMF) to 5-formyl-2-furancarboxylic acid (FFCA) when using water as solvent. The structure and composition of g-C3N4/NaNbO3 photocatalysts were characterized by TG, XRD, SEM, UV–Vis, FT-IR, and XPS methods, and the optical and electrochemical properties were investigated by EIS, PC, and PL techniques. O2? was inferred to be the primary active species in this process based on the active species trapping experiment. Heterostructure formation of g-C3N4/NaNbO3 composites efficiently promoted the separation of photo-generated electron-hole pairs and accelerated the electron transfer rate, thus reduced the formation of OH, and sequentially improved the selectivity of FFCA. The highest HMF conversion of 35.8% with FFCA selectivity of 87.4% was achieved on C/N-59.6 photocatalyst under the irradiation of visible light. The possible mechanism and reaction route were also proposed. |
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Keywords: | Photocatalytic oxidation 5-Hydroxymethylfurfural 5-Formyl-2-furancarboxylic acid Visible light |
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