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Highly dispersed carbon-supported Pd nanoparticles catalyst synthesized by novel precipitation–reduction method for formic acid electrooxidation
Authors:Yan Liang  Mengna Zhu  Juan Ma  Yawen Tang  Yu Chen  Tianhong Lu
Affiliation:aJiangsu Key Laboratory of New Power Batteries, Laboratory of Electrochemistry, College of Chemistry and Materials Science, Nanjing Normal University, 1# Wenyuan Road, Nanjing 210046, PR China;bInstitute of Chemical Power Sources, Soochow University, Suzhou 215006, PR China
Abstract:The highly dispersed and ultrafine carbon-supported Pd nanoparticles (Pd/C) catalyst is synthesized by using an improved precipitation–reduction method, which involves in PdII → PdO·H2O → Pd0 reaction path. In the method, palladium oxide hydrate (PdO·H2O) nanoparticles (NPs) with high dispersion is obtained easily by adjusting solution pH in the presence of 1,4-butylenediphosphonic acid (H2O3P-(CH2)4-PO3H2, BDPA). After NaBH4 reduction, the resulting Pd/C catalyst possesses high dispersion and small particle size. As a result, the electrochemical measurements indicate that the resulting Pd/C catalyst exhibits significantly high electrochemical active surface area and high electrocatalytic performance for formic acid electrooxidation compared with that prepared by general NaBH4 reduction method.
Keywords:Catalyst  Precipitation&ndash  reduction method  Formic acid  Electrooxidation  Electrocatalytic activity
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