Enthalpies of formation of some solid hafnium nickel compounds and of the Ni-Rich HfNi liquid by direct reaction calorimetry |
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Authors: | Najim Selhaoui Jean-Claude Gachon Jean Hertz |
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Affiliation: | (1) James Franck Institute, University of Chicago, Chicago, IL;(2) Laboratoire de Thermodynamique Métallurgique, University of Nancy Un, F-54506 Vandoeuvre Les Nancy Cedex, France |
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Abstract: | In the course of a systematic study of binary transition metal alloys, the enthalpies of formation of five Hf-Ni compounds
were measured by direct reaction calorimetry: Hf0.17Ni0.83(l/6HfNi5): ΔfH(1323 K) = − 37,000 J/mole of atoms (±3200) Hf0.22Ni0.781/9Hf2Ni7): Δf(1623 K) = −50,700 J/mole of atoms (±2000) Hf0.45Ni0.55(l/2OHf9Ni11): ΔfH(1473 K) = −54,500 J/mole of atoms (±2200) Hf0.50Ni0.50(l/2HfNi): ΔfH(1573 K) = −47,900 J/mole of atoms (±1800) Hf0.67Ni0.33(l/3Hf2Ni): ΔH(1423 K) = −36,700 J/mole of atoms (±1300) with reference to pure metals in their equilibrium states at the reaction
temperatures. The Ni-rich Hf-Ni liquid was also studied by the dissolution of Hf in the liquid alloy of variable composition
at 1743 and 1633 K. Results show that the enthalpy of formation of the liquid at a given composition depends strongly on temperature,
and this point suggests the existence of associations in the liquid. The melting temperature of Hf0.22Ni0.78(Hf2Ni7) which was found (1705 K) is slightly lower than the one (1743 K) given in the literature.
Formerly Senior Research Student with the Laboratoire de Thermodynamique Métallurgique, Université de Nancy Un, France |
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