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Interfacial polymerization preparation of functional paper coated with polyamide film containing volatile essential oil
Authors:Hideaki Ichiura  Masaru Takayama  Noriyoshi Nishida  Yoshito Otani
Affiliation:1. Department of Forest Sciences, Faculty of Agriculture, Kochi University, 200 Monobe‐Otsu, Nankoku, Kochi 783‐8502, Japan;2. Paper Ind. Res. Inst. Ehime Pref., 127 Otsu, Mendori‐cho, Shikokuchuo, Ehime 799‐0113, Japan
Abstract:An interfacial polymerization reaction was used to coat a functional paper with a polyamide film containing volatile essential oil (VEO) composites. The components of the VEO extract were linalool, α‐terpineol, carveol, carvone, perillaldehyde and valencene. Preparing the polyamide film by an interfacial polymerization reaction eliminated the need for microcapsule preparation and coating with a binder, which are typically used in functional paper preparation. The interfacial polymerization involved immersing a filter paper impregnated with an oil‐in‐water emulsion of ethylenediamine and VEO in a cyclohexane solution of terephthaloyl chloride. This successfully fixed the polyamide film containing the VEO on the paper surface. Release of VEO fragrance from the paper surface was studied, and the paper showed sustained release of the VEO. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
Keywords:polyamides  microencapsulation  coatings  functional paper  interfacial polymerization
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