溶剂芳香性对渣油沥青质稳定性的影响 |
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引用本文: | 施洋 贾燕子 杨清河 聂红. 溶剂芳香性对渣油沥青质稳定性的影响[J]. 石油炼制与化工, 2019, 50(12): 51-55 |
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作者姓名: | 施洋 贾燕子 杨清河 聂红 |
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作者单位: | 中国石化石油化工科学研究院 |
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摘 要: | 为深入认识固定床渣油加氢-催化裂化双向组合技术溶剂芳香性与沥青质稳定性的关系,采用Flory-Huggins模型考察了沙特轻质原油常压渣油的沥青质稳定性,并用溶解度参数关联了溶剂的芳香性。结果表明,Flory-Huggins模型可用于研究渣油体系的沥青质稳定性。随着溶剂芳香性的增加,其溶解度参数增大,沥青质稳定性增强。密度较大、H/C原子比较小的溶剂具有较大的溶解度参数,对沥青质的稳定性较有利。
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关 键 词: | 溶解度参数 芳香性 Flory-Huggins模型 沥青质稳定性 |
收稿时间: | 2019-03-26 |
修稿时间: | 2019-05-29 |
INFLUENCE OF SOLVENT AROMATICITY ON ASPHALTENE STABILITY |
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Abstract: | The relationship of solvent aromaticity and asphaltene stability of Saudi light AR in RICP technology was studied by Flory-Huggins model and the aromaticity of the solvent was correlated with the solubility parameter. The results proved the availability of Flory-Huggins model for measuring asphaltene stability in residue. The aspaltene stability increased with the increase of solvent/AR ratio. The aromaticity could be evaluated by solubility parameter. The solvent with higher density and lower molar ratio of H/C possessed higher solubility parameter and is beneficial to asphaltene stability. |
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Keywords: | solubility parameter aromaticity Flory-Huggins model asphaltene stability. |
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